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Some Investigation on the Corrosion of Iron

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Exercise 12

SOME INVESTIGATIONS ON THE CORROSION OF IRON

  1. Introduction
  1. Principle
    Corrosion is the process in which the metal returns to its natural state (insert citation). This deterioration happens when the metal undergoes a spontaneous oxidation, most likely when in contact with oxygen. Through time this reaction occurs but this electrochemical process  is often accompanied by mechanical or physical stress.

    In iron, a metal alloy, the formation of rust develops with the reduction-oxidation  reaction. These are the redox half-reactions involved in rusting:
    (insert reaction)

  1. Objectives

The objective of this exercise is to state the effects of the following factors in the corrosion of iron:

  1. acidity and basicity of the solution in contact with the metal;
  2. mechanical stress applied on the metal; and
  3. contact with other metals.
  1. Materials
  1. Reagents

NaOH        KOH        Na3PO4        distilled H2O                agar                zinc strip
NaCl        KNO
3        NaSCN        0.1M K3Fe(CN)6                nails                phenolphthalein
HCl        HNO
3        H2SO4        ferrous sulfate solution        copper strip        litmus paper

  1. Apparatus

test tubes                stirring rod                hot plate        iron ring
centrifuge tubes        400-mL beaker                iron stand
bunsen burner                250-mL beaker                wire gauze

  1. Procedure
  1. Reactions of Iron with various Aqueous Solutions

  1. Preparation of Agar Medium

  1. Reactions of Iron as affected by Mechanical Stress
  1. Reactions Involving Metal Couples – Two Metals in Contact
  1. Data/Observations

Table 12.1. The pH of different solutions on Set A, B, & C.

Solutions

pH
(acidic, basic, neutral)

NaOH

Basic

NaCl

Neutral

HCl

Acidic

KOH

Basic

KNO3

Neutral

HNO3

Acidic

Na3PO4

Basic

NaSCN

Neutral

H2SO4

Acidic

distilled H2O

Neutral

Table 12.2. Observations on the changes on the nails in the solutions.x

Solutions

Observation/s

NaOH

No changes

NaCl

Rusting occurred

HCl

Black discoloration on nails, formation of black precipitate

KOH

No changes

KNO3

Rusting occurred

HNO3

Rusting occurred

Na3PO4

No changes

NaSCN

Rusting occurred, formation of orange precipitate

H2SO4

The nail was dissolved, formation of black precipitate

distilled H2O

Rusting occurred

...

...

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