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How to Calculate Standard Deviation

Essay by   •  March 17, 2016  •  Lab Report  •  358 Words (2 Pages)  •  1,261 Views

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Table 1: volume of stock and water (ml), mass of phosphorus (µg), absorbance at 660nm

Mass of phosphorus (µg)

Volume of stock and water (5mL)

                          Absorbance at 660 nm

          1

           2

       average

10

0.1 + 4.9

    0.034

        0.037  

      0.036

20

0.2 + 4.8

    0.057

        0.082

0.069

30

0.3 + 4.7

    0.097

       0.086

0.091

40

0.4 + 4.6

    0.111

       0.143

0.127

50

0.5 + 4.5

    0.140

       0.166

0.153

Unknown x

5

    0.038

      0.035

0.036

Unknown y

5

    0.108

      0.104

0.106

Sample calculation to show the volume of stock:

There is 100 (µg) of phosphorus in 1 mL of phosphate solution

Therefore, 10 (µg) of phosphorus will be =  = 0.1 mL of phosphate solution[pic 1]

The calculation is repeated to find the stock solution for 20, 30, 40 and 50 (µg) of phosphorus respectively.

[pic 2]

Figure 1: the graph representing the relationship between absorbance at 660nm and the mass of phosphorus (µg).

To find the mass of phosphorus from the standard curve,

For unknown X

Given, y = 0.003x

0.036 = 0.003x

Therefore, x = 12 (µg)

Concentration of unknown x = 12 / 5 = 2.4(µg/mL)

For unknown Y

Given, y = 0.003x

0.106 = 0.003x

Therefore, x = 35.3 (µg)

Concentration of unknown y = 35.3 / 5 = 7.06 (µg/mL)

Calculation to find the standard deviation for unknown X and Y

Formula for standard deviation,

S =  [pic 3]

Unknown x1,

From graph, y= 0.003x

0.038 = 0.003x

Therefore, x = 12.7 (µg)

Concentration for x1, 12.7 / 5 = 2.5(µg/mL)

Unknown x2,

From graph, y= 0.003x

0.035 = 0.003x

Therefore, x = 11.7 (µg)

Concentration for x2, 11.7 /5 = 2.3(µg/mL)

Hence, the standard deviation for the average concentration

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